CORRECTION OF HOLLOWAYS (1977) ADAPTATION OF THE MODIFIED REDLICH-KWONG EQUATION OF STATE FOR CALCULATION OF THE FUGACITIES OF MOLECULAR-SPECIES IN SUPERCRITICAL FLUIDS OF GEOLOGIC INTEREST

被引：95

作者：

FLOWERS, GC

机构：

[1] Department of Geology and Geophysics, University of California, Berkeley, 94720, California

来源：

CONTRIBUTIONS TO MINERALOGY AND PETROLOGY | 1979年 / 69卷 / 03期

关键词：

D O I：

10.1007/BF00372333

中图分类号：

P3 [地球物理学]; P59 [地球化学];

学科分类号：

0708 ; 070902 ;

摘要：

Consideration of constraints imposed on fugacity coefficients by the Gibbs-Duhem equation and those inherent in the Redlich-Kwong equation of state (Redlich and Kwong, 1949) and its modification by de Santis et al. (1974) indicates that Holloway's (1977) adaptation of the Redlich-Kwong equation for calculating fugacity coefficients of molecular species in gas mixtures is in error. Revised calculations using the correct equation lead to much smaller departures from ideality than those generated by Holloway. © 1979 Springer-Verlag.

引用

页码：315 / 318

页数：4

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