EXCESS ENTHALPY FOR THE BINARY-SYSTEM 1,3-DIOXOLANE + HALOTHANE

被引：4

作者：

FRANCESCONI, R

COMELLI, F

GIACOMINI, D

机构：

[1] CNR,CTR STUDIO FIS MACROMOLEC,I-40126 BOLOGNA,ITALY

[2] CNR,ICOCEA,IST COMPOSTI CARBONIO,BOLOGNA,ITALY

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1990年 / 35卷 / 02期

关键词：

D O I：

10.1021/je00060a029

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The excess molar enthalpies HEof the 1,3-dioxolane + halothane binary system were determined at atmospheric pressure, at 288.15 and 298.15 K by an isothermal flow microcalorimeter. The mixtures studied are highly exothermic, HE< 0, with almost symmetrical HEvs composition curves and with positive molar excess heat capacity, CEE= dHE/dT. This suggests complex formation in the liquid mixture, via hydrogen bonding. © 1990, American Chemical Society. All rights reserved.

引用

页码：190 / 191

页数：2

共 8 条

[1]

BENSON GC, 1974, INT DATA SER SEL D A, P19

[2] VAPOR LIQUID EQUILIBRIUM, EXCESS GIBBS ENERGY AND EXCESS ENTHALPY OF 1,3 DIOXOLANE-METHYLCYCLOHEXANE AT T = 313.15-K [J].