METALLOORGANIC LIQUID-CRYSTALS - BIS(N-ARYL-4-SUBSTITUTED SALICYLALDIMINE)NICKEL(II) AND BIS(N-ARYL-4-SUBSTITUTED SALICYLALDIMINE)COPPER(II) COMPLEXES

被引：38

作者：

MARCOS, M

ROMERO, P

SERRANO, JL

机构：

[1] Química Orgánica, Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza—CSIC

来源：

CHEMISTRY OF MATERIALS | 1990年 / 2卷 / 05期

关键词：

D O I：

10.1021/cm00011a007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis and mesogenic behavior of new metalloorganic complexes are described: the bis(N-aryl-4-[((decyloxy)benzoyl)oxy]salicylaldimine)nickel(II) and -copper(II) in which aryl = C6H4OCnH2n+1 and n = 1–6,8,10,14. All the copper(II) complexes show liquid-crystal properties (nematic and/or smectic C phases) with a broad temperature range, whereas nickel(II) complexes show fluid liquid-crystal properties (nematic mesophase) when n = 1, 2, 3, 4. © 1990, American Chemical Society. All rights reserved.

引用

页码：495 / 498

页数：4

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