ORGANO-ANTIMONY COMPOUNDS .8. CLEAVAGE OF SB-O-SB BONDS IN MU-OXYBIS(TRIPHENYLCHLOROANTIMONY) AND TRIPHENYLANTIMONY OXIDE BY METHANOL AND ACETYLACETONE

被引：31

作者：

GOEL, RG

RIDLEY, DR

机构：

[1] Guelph-Waterloo Centre for Graduate Work in Chemistry, University of Guelph, Guelph

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94384-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

SbOSb bonds in (Ph3ClSb)2O and PH3SbO are cleaved readily by methanol and acetylacetone. The reactions provide convenient synthetic routes for Ph3Sb(OMe)Cl, Ph3Sb(OMe)2, Ph3Sb(acac)Cl, and Ph3Sb(acac)OH. Characterization of these compounds by infrared, Raman, and 1H NMR spectral measurements is reported. © 1979.

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页码：207 / 212

页数：6

相关论文

共 20 条

[1]

BEAUCHAMP AL, 1969, J AM CHEM SOC, V91, P267

[2] INFRARED SPECTRA AND STRUCTURE OF ACETYLACETONATO PLATINUM(2) COMPLEXES .I. INFRARED SPECTRA AND NORMAL COORDINATE ANALYSIS OF POTASSIUM DICHLORO(ACETYLACETONATO)PLATINATE(2) [J].

BEHNKE, GT ;

NAKAMOTO, K .

INORGANIC CHEMISTRY, 1967, 6 (03) :433-&

[3]

BONATI F, 1966, ORGANOMET CHEM REV, V1, P379

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF "MU-OXY-BIS(TRIPHENYLAZIDOANTIMONY), APPENTAVALENT ANTIMONY DERIVATIVE WITH METAL-OXYGEN-METAL BONDS [J].

FERGUSON, G ;

RIDLEY, DR .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, 29 (OCT15) :2221-2226

[5]

FERGUSON G, 1971, CHEM COMMUN, P1549

[6] ORGANOANTIMONY COMPOUNDS .3. FAR-INFRARED AND RAMAN SPECTROSCOPIC STUDIES ON TRIORGANOANTIMONY(V) DERIVATIVES, R3SBX2 [J].

GOEL, RG ;

MASLOWSK.E ;

SENOFF, CV .

INORGANIC CHEMISTRY, 1971, 10 (11) :2572-&

[7] ORGANOANTIMONY COMPOUNDS .7. PREPARATION AND CHARACTERIZATION OF COMPLEX TRIORGANOANTIMONY(V) CATIONS, R3 SBL-2+(2) [J].

GOEL, RG ;

PRASAD, HS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 59 (OCT1) :253-257

[8] ORGANOANTIMONY COMPOUNDS .6. OXYBIS(TRIORGANOANTIMONY) DIPERCHLORATES AND THEIR COMPLEXES WITH OXYGEN-DONOR LEWIS BASES [J].

GOEL, RG ;

PRASAD, HS .

INORGANIC CHEMISTRY, 1972, 11 (09) :2141-&

[9] ORGANOANTIMONY COMPOUNDS .5. STUDIES ON TRIMETHYLANTIMONY(V) AND TRIPHENYLANTIMONY(V) DERIVATIVES OF HALOACETIC ACIDS [J].

GOEL, RG ;

RIDLEY, DR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 38 (01) :83-&

[10] ORGANOANTIMONY(V) PSEUDOHALIDES [J].

GOEL, RG ;

RIDLEY, DR .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1971, 7 (01) :21-&