ENERGY MIGRATION IN DIBLOCK COPOLYMER MICELLES AND BRUSHES

被引:12
作者
LIU, GJ
机构
[1] Department of Chemistry, University of Calgary, Calgary, Alta. T2N 1N4, 2500 University Drive, NW
关键词
D O I
10.1021/j100015a032
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Energy migration experiments in diblock copolymer micelles and brushes were proposed. Expressions for the transient donor and acceptor fluorescence intensities and the energy-trapping efficiency were derived for the described experiments. By following the proposed data treatment procedure, the core radii of micelles and the thickness of a brush layer can be evaluated. The dependence of energy migration coefficient D-m on n(D), the number of donor groups in each chain, can be used to check the validity of the proposed models.
引用
收藏
页码:5465 / 5470
页数:6
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