5-FORMYL-DELTA-VALEROLACTONE - A USEFUL SYNTHON FOR THE CHIRAL SYNTHESIS OF THE VESPA-ORIENTALIS PHEROMONE AND THE MOSQUITO OVIPOSITION ATTRACTANT PHEROMONE

被引：28

作者：

COUTROT, P

GRISON, C

BOMONT, C

机构：

[1] Institut Nancéien de Chimie Moléculaire, Laboratoire de Chimie Organique II, associé au CNRS, 54506 Vandoeuvre-lès-Nancy, Nancy 1

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)74412-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A synthetic scheme starting from the reaction between the lithiated N-allyl-N-methyl-(bisdimethylamino)phosphoramide anion and the triflate derivative of (R)-(-)- or (S)-(+)-2,3-O-isopropylideneglycerol is described to prepare the key chiral synthon (R)-5- or (S)-5-formyl-delta-valerolactone that leads to the title compounds.

引用

页码：8381 / 8384

页数：4

共 31 条

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