THE BINARY REAGENT PHSECL-ZNCL2 - A POWERFUL CHLORO-PHENYLSELENENYLATING AGENT OF ELECTROPHILIC OLEFINS

被引：14

作者：

DONOFRIO, F ^{[1
]}

PARLANTI, L ^{[1
]}

PIANCATELLI, G ^{[1
]}

机构：

[1] UNIV ROMA LA SAPIENZA,CNR,CTR STUDIO CHIM SOSTANZE ORGAN NAT,DIPARTMENTO CHIM,I-00185 ROME,ITALY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 11期

关键词：

D O I：

10.1016/0040-4039(95)00159-A

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The binary reagent PhSeCl-ZnCl2 was found to be powerful for the stereocontrolled conversion of highly electrophilic olefins, such as maleate and fumarate esters, into the corresponding chloro phenylseleno derivatives in very high yields. Other olefins, such as methyl acrylate and methyl vinyl ketone, react virtually instantaneously.

引用

页码：1929 / 1932

页数：4

共 5 条

[1] FREE-RADICAL ADDITIONS OF DISELENIDES TO DIMETHYL ACETYLENEDICARBOXYLATE, METHYL PROPIOLATE, AND DIMETHYL MALEATE [J].