LIMITING CONVERSIONS IN 2-PHASE POLYMER REACTIONS

被引：20

作者：

SUNDBERG, DC

JAMES, DR

机构：

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1978年 / 16卷 / 02期

关键词：

FLOW OF FLUIDS - Two Phase - MONOMERS - POLYBUTADIENES - Latex - POLYSTYRENES - Latex;

D O I：

10.1002/pol.1978.170160224

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The concepts of limiting conversion in one-phase polymer reactions have been extended to two-phase reaction systems. The analysis of the two-phase reaction requires the consideration of the glass transition temperature of each phase and the distribution of the reacting monomer between the phases. Predicted limiting conversions are compared with experimental data for simple polystyrene and polystyrene-polybutadiene reactions in latex form. Strong agreement is found for these comparisons.

引用

页码：523 / 529

页数：7

共 9 条

[1]

BUECHE F, 1962, PHYSICAL PROPERTIES, P116

[2]

FLORY PJ, 1953, PRINCIPLES POLYM CHE, P127

[3] KINETICS OF METHYL-METHACRYLATE EMULSION POLYMERIZATION [J].