PREPARATION OF CYCLOHEX-2-ENE-1,4-DIONES

被引：23

作者：

CHAPMAN, DD

MUSLINER, WJ

GATES, JW

机构：

[1] Research Laboratories, Eastman Kodak Company, Rochester

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 01期

关键词：

D O I：

10.1039/j39690000124

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl substituted cyclohex-2-ene-1,4-diones have been prepared by the pyrolysis of the appropriate 2,3,4a,5,8,8a-hexahydro-5,8-methanonaphthoquinones. The stereochemistry of some of these intermediates is discussed and the extension of the synthesis to monoacetals of cyclohex-2-ene-1,4-diones is described.

引用

页码：124 / &

共 16 条

[1] DARSTELLUNG VON PARA-CHINON-EPOXYDEN [J].

ALDER, K ;

FLOCK, FH ;

BEUMLING, H .

CHEMISCHE BERICHTE-RECUEIL, 1960, 93 (08) :1896-1899

[2]

ALDER K, 1929, BER DTSCH CHEM GES B, V62, P2337

[3]

ALDER K, 1933, LIEBIGS ANN CHEM, V501, P247

[4] HYDROGENATION OF SOME QUINONES TO ENEDIONES [J].

BIRCH, AJ ;

WALKER, KAM .

TETRAHEDRON LETTERS, 1967, (36) :3457-&

[5] REDUCTION PRODUCTS OF CYCLOPENTADIENE-BENZOQUINONE ADDUCT [J].

COOKSON, RC .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (MAR) :2023-&

[6] THE DIRECT FORMATION OF CYCLOPENTANONES BY THE ACTION OF MINERAL ACIDS ON CARBOXY-ADIPIC ACIDS AND RELATED COMPOUNDS [J].

CROMBIE, L ;

HANCOCK, JEH ;

LINSTEAD, RP .

JOURNAL OF THE CHEMICAL SOCIETY, 1953, (NOV) :3496-3504

[7]

EMSLEY JW, 1965, HIGH RESOLUTION NUCL, V1, P357

[8] CYCLOHEX-2-ENE-1,4-DIONE [J].

GARBISCH, EW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (21) :4971-&

[9]

GARBISCH EW, 1964, CHEM IND-LONDON, P1715

[10] COMMENTS ON N.M.R. SPECTRA OF XNAA]XN] TYPE [J].

HARRIS, RK .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1964, 42 (10) :2275-&

← 1 2 →