RADIATION-INDUCED CHANGES IN THE STRUCTURE OF CIS-1,4-POLYBUTADIENE

被引:7
作者
BURNAY, SG
机构
[1] Materials Development Division, AERE Harwell, Didcot, Oxford, England
来源
RADIATION PHYSICS AND CHEMISTRY | 1979年 / 13卷 / 5-6期
关键词
D O I
10.1016/0146-5724(79)90042-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The processes occurring during electron irradiation of cis-polybutadiene have been investigated. The concentration of unsaturated bonds decays during irradiation with the formation of intermolecular crosslinks, intramolecular cyclic structures and polyene groups. The decay processes can be described by equations which approximate to first order kinetics. Rate constants for the decay processes have been estimated from the experimental data. © 1979.
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页码:171 / 180
页数:10
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