THE X-RAY CRYSTAL-STRUCTURES OF THE CADMIUM COMPLEXES OF PYRIDINE-1-THIOL AND MERCAPTOBENZOTHIAZOLE, [CD(C5H4NS)2]N AND [CD(C7H4N2S2)2]N - 2 UNUSUAL VOLATILE POLYMERIC COMPLEXES

被引：70

作者：

HURSTHOUSE, MB

KHAN, OFZ

MAZID, M

MOTEVALLI, M

OBRIEN, P

机构：

[1] Department of Chemistry, Queen Mary and Westfield College, London, E1 4NS, Mile End Road

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)86231-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures of the 2:1 complexes formed by pyridine-1-thiol (I) and mercaptobenzothiazole (II) with cadmium(II) are polymeric but both sublime at reduced pressure and decompose cleanly to CdS in air. Both structures contain approximately octahedrally-coordinated cadmium atoms (CdN2S4) and involve bridging and chelating modes for the ligand. © 1990.

引用

页码：541 / 544

页数：4

共 13 条

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