SYNCHRONOUS MECHANISM OF THE 1,1-CYCLOADDITION OF NITRILE YLIDES TO C=C DOUBLE-BONDS

被引：18

作者：

FISCHER, J

STEGLICH, W

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-5300 BONN 1,FED REP GER

[2] EGYT PHARMACOCHEM WORKS,H-1475 BUDAPEST,HUNGARY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1002/anie.197901671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An insight into the mode of reaction of nitrile ylides such as 1 has come from the study of their intramolecular cyloaddition to double bonds. The formation of 2a and 2b in the ratio 9:1 is assessed as indicating a synchronous mechanism (RpCL—C6H4). (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

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页码：167 / 168

页数：2

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