VAPOR-PRESSURES OF AQUEOUS-SOLUTIONS OF (AG, TI, CA)NO3 AT 371.7-K

被引：15

作者：

SANGSTER, J ^{[1
]}

ABRAHAM, MC ^{[1
]}

ABRAHAM, M ^{[1
]}

机构：

[1] UNIV MONTREAL,DEPT CHEM,MONTREAL H3C 3V1,QUEBEC,CANADA

来源：

JOURNAL OF CHEMICAL THERMODYNAMICS | 1979年 / 11卷 / 07期

关键词：

D O I：

10.1016/0021-9614(79)90027-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Vapour pressures of (Ag, Tl, Ca)NO3 + H2O have been measured by the static technique at 371.65 K. The mole ratio n(Ag) n(Tl) was held at 1.06, the mole fraction of calcium in the melt was varied between 0 and 0.125, and the mole fraction of H2O was varied over essentially its complete range. The results have been interpreted and discussed in terms of Raoult's law, B.E.T. isotherms, and excess Gibbs energy. The present results, compared with those found previously for (Ag, Tl, Cd)NO3 + H2O, indicate that Ca2+ and Cd2+ are very similar in their effects upon the Gibbs energies studied here, and are hydrated to nearly the same extent. © 1979.

引用

页码：619 / 625

页数：7

共 6 条

[1]

BRAUNSTEIN J, 1971, IONIC INTERACTIONS D, V1, pCH4

[2]

BRAUNSTEIN J, 1971, J CHEM THERMODYN, V3, P419

[3]

DARMOIS E, 1960, ELECTROCHIMIE THEORI, P18

[4]

ROBINSON RA, 1965, ELECTROLYTE SOLUTION, P461

[5] VAPOR-PRESSURES OF AQUEOUS-SOLUTIONS OF (AG, TL, CD)NO3 AT 98.5-DEGREES-C .1. BRUNAUER-EMMETT-TELLER ISOTHERMS [J].

SANGSTER, JM ;

ABRAHAM, MC ;

ABRAHAM, M .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (03) :348-351

[6]

TRUDELLE MC, 1977, CAN J CHEM, V55, P1713, DOI 10.1139/v77-242

← 1 →