ATOM SIZES AND BOND LENGTHS IN MOLECULES AND CRYSTALS

被引：588

作者：

OKEEFFE, M

BRESE, NE

机构：

[1] Contribution from the Department of Chemistry, Arizona State University, Tempe

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1991年 / 113卷 / 09期

关键词：

D O I：

10.1021/ja00009a002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Atom size parameters are derived for 75 elements. In conjunction with an ''electronegativity'' parameter, these can be used to determine bond valence parameters and hence to derive bond lengths for a wide variety of homopolar, heteropolar, and metallic bonds. The size parameter of an atom is close to the distance from the nucleus at which the electrostatic potential is equal to the first ionization potential.

引用

页码：3226 / 3229

页数：4

共 27 条

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