A SIMPLE, HIGH-YIELDING PREPARATION OF SODIUM DIISOPROPYLAMIDE AND OTHER SODIUM DIALKYLAMIDES

被引：22

作者：

BARR, D

DAWSON, AJ

WAKEFIELD, BJ

机构：

[1] UNIV SALFORD,DEPT CHEM & APPL CHEM,COCKCROFT BLDG,SALFORD M5 4WT,LANCS,ENGLAND

[2] ASSOCIATED OCTEL CO LTD,WIRRAL L65 4HF,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 02期

关键词：

D O I：

10.1039/c39920000204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sodium dialklamides are prepared by the reaction of sodium dispersion with secondary amines in the presence of isoprene.

引用

页码：204 / 204

页数：1

共 14 条

[1] BRANDSMA L, 1987, PREPARATIVE POLAR OR, V1
[2] GAUDEMARBARDONE F, 1979, SYNTHESIS-STUTTGART, P469
[3] TRIMETHYLSILYLMETHYLPOTASSIUM AND OTHER OUTSTANDING METALLATING AGENTS
HARTMANN, J
SCHLOSSER, M
[J]. HELVETICA CHIMICA ACTA, 1976, 59 (02) : 453 - 466
[4] ON THE DIRECT METALATION OF ISOPRENE
KLUSENER, PAA
TIP, L
BRANDSMA, L
[J]. TETRAHEDRON, 1991, 47 (10-11) : 2041 - 2064
[5] INTERACTION OF ALKOXIDES .16. NEW PROPERTIES OF COMPLEX BASES FORMED FROM BUTYLLITHIUM AND HEAVIER ALKALI-METAL TERT-PENTOXIDES AT VARIOUS ALKOXIDE CONCENTRATIONS - REACTION WITH ORGANIC HALOGENIDES
LOCHMANN, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 364 (03) : 281 - 288
[6] INTERACTIONS OF ALKOXIDES .11. REACTIONS OF SUBSTITUTED N-LITHIUM AMIDES WITH HEAVIER ALKALI-METAL ALKOXIDES - NOVEL METHOD FOR THE PREPARATION OF N-SODIUM AND N-POTASSIUM DIALKYLAMIDES
LOCHMANN, L
TREKOVAL, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 179 (02) : 123 - 132
[7] INTERACTIONS OF ALKOXIDES .17. PROPERTIES OF COMPLEX BASES FROM ORGANO-LITHIUM COMPOUNDS AND VARIOUS SODIUM ALKOXIDES AFFECTED BY THE STRUCTURE AND CONCENTRATION OF THE ALKOXIDE
LOCHMANN, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 376 (01) : 1 - 6
[8] Morrison R. C., 1986, U.S. Patent, Patent No. [4,595,779, 4595779]
[9] ORGANOSELENIUM CHEMISTRY .4. DEPROTONATIONS WITH POTASSIUM DIISOPROPYLAMIDE-LITHIUM TERT-BUTOXIDE - ALKYLATION OF 1-(PHENYLSELENO)ALKENES AND BIS(PHENYLSELENO) ACETALS
RAUCHER, S
KOOLPE, GA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (19) : 3794 - 3796
[10] REETZ MT, 1980, LIEBIGS ANN CHEM, P1471

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