FACILE N-H CLEAVAGE OF AMMONIA

被引：63

作者：

KOELLIKER, R

MILSTEIN, D

机构：

[1] Department of Organic Chemistry the Weizmann, Institute of Science, Rehovot

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 06期

关键词：

D O I：

10.1002/anie.199107071

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dinuclear Ir complex 1 already reacts with excess NH3 at - 50-degrees-C to give not only mono- and dicationic complexes but also 2, the first amido-olefin complex. An N-H activation under such exceptionally mild conditions is of interest for the catalytic functionalization of olefins with NH3.

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收藏

页码：707 / 709

页数：3

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