INTRAMOLECULAR FREE-RADICAL CYCLIZATIONS USING ACYLSILANES AS RADICALPHILES

被引：70

作者：

TSAI, YM

CHERNG, CD

机构：

[1] Department of Chemistry, National Taiwan University, Taipei

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 29期

关键词：

RADICAL CYCLIZATION; ACYLSILANE; RADICAL BROOK REARRANGEMENT; RADICAL ADDITION TO CARBONYL; CYCLOPENTANOL;

D O I：

10.1016/0040-4039(91)80820-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carbon radicals add intramolecularly to acylsilanes at the carbonyl carbon followed by radical Brook rearrangement to give silylated cyclopentanols or cyclohexanols in good yields.

引用

页码：3515 / 3518

页数：4

共 44 条

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[7] GAS-PHASE DETERMINATION OF THE GEOMETRIC REQUIREMENTS OF THE SILICON BETA-EFFECT - PHOTOELECTRON AND PENNING IONIZATION ELECTRON SPECTROSCOPIC STUDY OF SILYLTHIIRANES AND SILYL-OXIRANES - SYNTHESIS AND CHEMISTRY OF TRANS-2,3-BIS(TRIMETHYLSILYL)THIIRANE
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[8] TANDEM FREE-RADICAL RING EXPANSION AND 5-EXO-DIG 5-HEXYNYL RADICAL CYCLIZATION - A USEFUL APPROACH TO FUSED BICYCLIC CARBOCYCLES
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