SONOCHEMISTRY - A SYSTEMATIC STUDY OF THE MALEATE-FUMARATE ISOMERIZATION IN THE PRESENCE OF ALKYL BROMIDES

被引：19

作者：

REISSE, J

YANG, DH

MAECK, M

VANDERCAMMEN, J

VANDERDONCKT, E

机构：

[1] Université Libre de Bruxelles, B 1050 Bruxelles, CP 165

来源：

ULTRASONICS | 1992年 / 30卷 / 06期

关键词：

QUANTITATIVE SONOCHEMISTRY; RADICAL INDUCED CIS TRANS ISOMERIZATION;

D O I：

10.1016/0041-624X(92)90096-5

中图分类号：

O42 [声学];

学科分类号：

070206 ; 082403 ;

摘要：

A systematic and quantitative study of diethyl maleate-diethyl fumarate induced isomerization has been performed in CCl4 using different 'inert' gases, different initiators and various experimental conditions. It was shown how changes in the experimental conditions, generally considered as minor in thermochemistry, can have dramatic effects in sonochemistry (for example, the 'marble effect').

引用

页码：397 / 401

页数：5

共 31 条

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