SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF RUTHENIUM COMPLEXES OF THE LACUNARY KEGGIN POLYOXOANION - [SIW(11)O(39)RUL](N-), L=H2O, NO, N-2

被引：47

作者：

FILIPEK, K

机构：

[1] Fakultät für Chemie der Universität

来源：

INORGANICA CHIMICA ACTA | 1995年 / 231卷 / 1-2期

关键词：

POLYTUNGSTATE COMPLEXES; RUTHENIUM COMPLEXES; NITROSYL COMPLEXES; DINITROGEN COMPLEXES; SMALL MOLECULE ACTIVATION;

D O I：

10.1016/0020-1693(94)04347-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The modified synthesis of the monosubstituted Keggin compound K-5[SiW11O39RuIII(H2O)]. 8H(2)O is presented. The product was characterized by elemental analysis, IR spectroscopy, FAB mass spectrometry and electrochemistry. Furthermore, an aquo ligand was replaced by NO and then the nitrosyl compound was reduced to form a dinitrogen complex. The reactivity of the latter compound was examined.

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页码：237 / 239

页数：3

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