PERFLUOROPHENYL DERIVATIVES OF ELEMENTS .19. REACTIONS OF SOME POLYFLUOROBENZYNE DERIVATIVES

被引：19

作者：

COHEN, SC

REDDY, MLN

ROE, DM

TOMLINSO.AJ

MASSEY, AG

机构：

[1] Department of Chemistry, Queen Mary College

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 14卷 / 02期

基金：

英国生物技术与生命科学研究理事会;

关键词：

D O I：

10.1016/S0022-328X(00)87663-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of 2-chlorononafluorobiphenyl is described but it cannot be obtained by decomposing pentafluorophenyllithium in the presence of chloropentafluorobenzene. Tetrafluorobenzyne adds to styrene to give 1,2,3,4-tetrafluorophenanthrene and 1,2,3,4-tetrafluorodihydrophenanthrene. 2,2′-Dilithiooctafluorobiphenyl readily loses one molecule of lithium fluoride at 0° to give 1-lithioheptafluorobiphenylene from which other substituted heptafluorobiphenylenes may be synthesised. © 1968.

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页码：241 / &

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