REDUCTION OF QUINONES AND QUINONEMONOSULFONIMIDES WITH N,N-DIETHYLHYDROXYLAMINE

被引：29

作者：

FUJITA, S

SANO, K

机构：

[1] Research Laboratories, Askigara, Fuji Photo Film Co., Ltd., Minami-Ashigara

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 15期

关键词：

D O I：

10.1021/jo01329a012

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Quinones (1) and quinonemonosulfonimides (3a-e and 5) are reduced with A. N-diethylhydroxylamine (DEH) to give the corresponding hydroquinones (2) and sulfonylaminophenols (4a-e and 6), respectively. The DEH reduction is a key step in an improved synthetic route to dye developers (lla-c and 12a-c). Nitrone-hydroquinone 1 : 1 complexes (14a-f) are isolated as intermediates. © 1979, American Chemical Society. All rights reserved.

引用

页码：2647 / 2651

页数：5

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