A NEW FRAMEWORK FOR UNDERSTANDING RELAXOR FERROELECTRICS

被引:153
作者
THOMAS, NW
机构
[1] School of Materials, The University of Leeds, Leeds
关键词
FERROELECTRIC; RELAXOR; PEROVSKITE; ELECTROCERAMIC;
D O I
10.1016/0022-3697(90)90025-B
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new theoretical framework is presented for understanding the dielectric response of relaxor ferroelectrics. The theory is developed by reference to the dielectric response of lead magnesium niobate, a well-known relaxor material. The existence is proposed of a ferroelectric network linking niobium-oxygen coordination octahedra, where the temperature at which a given octahedron becomes decoupled from this network depends on its local coordination by other niobium-oxygen octahedra. This dependence permits the definition of a Curie point distribution function, which expresses the number of octahedra being decoupled from the network at a given temperature, as a function of temperature. The real part of the permittivity, episilon'-r, is simulated by convoluting the Curie point distribution function with a simple dielectric response function, phi-E(T), and an explanation is given for the frequency dependence of epsilon'-r. The imaginary part of the permittivity, epsilon'-r, is interpreted by regarding the decoupling of NbO6 octahedra from the ferroelectric network as a relaxation process. The role of ferroelectric microregions and microregion walls is discussed, and the contribution of the theoretical framework to the future development and exploitation of relaxor materials is assessed.
引用
收藏
页码:1419 / 1431
页数:13
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