PHOTOCATALYTIC ONE-STEP SYNTHESES OF CYCLIC IMINO ACIDS BY AQUEOUS SEMICONDUCTOR SUSPENSIONS

被引:72
作者
OHTANI, B [1 ]
TSURU, S [1 ]
NISHIMOTO, S [1 ]
KAGIYA, T [1 ]
IZAWA, K [1 ]
机构
[1] AJINOMOTO CO INC,CENT RES LABS,KAWASAKI KU,KAWASAKI,KANAGAWA 210,JAPAN
关键词
D O I
10.1021/jo00308a005
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
: Optically active cyclic imino acids, pipecolinic acid and proline, are readily obtained from α,ω-diamino carboxylic acids and their Nw-substituted derivatives by the photoirradiation of aqueous suspensions of TiO2 or CdS loaded with platinum oxides under Ar at room temperature. © 1990, American Chemical Society. All rights reserved.
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页码:5551 / 5553
页数:3
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