LITHIUM-INDUCED CYCLIZATION OF TRIBENZO CYCLOTRIYNES

被引：32

作者：

YOUNGS, WJ

DJEBLI, A

TESSIER, CA

机构：

[1] Department of Chemistry, The University of Akron, Akron

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 07期

关键词：

D O I：

10.1021/om00053a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new lithium-induced alkyne cyclization reaction of cyclotriynes leads to the formation of a fulvalene dianion derivative in high yield, as confirmed by X-ray crystallography. This unprecedented reaction may be useful for the synthesis of a variety of fulvalene dianions, and these may be used in the synthesis of extended metallocene complexes.

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页码：2089 / 2090

页数：2

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