CYCLOADDITION REACTIONS OF DIMETHYL MALEATE AND FUMARATE WITH CYCLOPENTADIENE ON GAMMA-ALUMINA - COMPETING MECHANISMS FOR EPIMERIZATION OF THE DIELS-ALDER ADDUCTS

被引：12

作者：

BAINS, S ^{[1
]}

PAGNI, RM ^{[1
]}

KABALKA, GW ^{[1
]}

机构：

[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 41期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)93523-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder adducts, formed in the reaction of cyclopentadiene and dimethyl maleate and fumarate, epimerize on gamma-alumina by competing mechanisms involving the retro-Diels-Alder reaction and enolates.

引用

页码：5663 / 5666

页数：4

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