ISOTOPIC DISTRIBUTIONS IN EXOTHERMIC ION-MOLECULE REACTIONS . A SIMPLE MODEL

被引：32

作者：

LIGHT, JC

CHAN, S

机构：

[1] Department of Chemistry, James Franck Institute, University of Chicago, Chicago

[2] Argonne National Laboratory, Argonne, IL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 51卷 / 03期

关键词：

D O I：

10.1063/1.1672098

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A simple model of exothermic ion-molecule reaction is proposed in which the isotopic distribution of products is due to the separations of the center of charge from the center of mass of the diatomic reactant. Applications to the energy dependence of the isotope ratio of products of the reactions Ar+HD + and Kr+HD+ indicate that this factor may be predominant in the energy range of 1-10 eV (center of mass).

引用

页码：1008 / &

共 19 条

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