SYNTHESIS AND CHARACTERIZATION OF A PYRAZINE BRIDGED BIS-ALLYL RUTHENIUM(IV) COMPLEX - CRYSTAL-STRUCTURE OF [((ETA-3-ETA-3-C10H16)RUCL2)2(MU-C4H4N2)].2CHCL3

被引:20
作者
STEED, JW [1 ]
TOCHER, DA [1 ]
机构
[1] UNIV LONDON UNIV COLL, DEPT CHEM, 20 GORDON ST, LONDON WC1H 0AJ, ENGLAND
关键词
D O I
10.1016/0022-328X(91)86092-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of pyrazine with the ruthenium(IV) bis-ally] dimer [(eta-3:eta-3-C10H16)RuCl(mu-Cl)]2 gives the bridged binuclear complex [{(eta-3:eta-3-C10H16)RuCl2}2(mu-C4H4N2)] in high yield. The complex has been characterised by H-1 NMR spectroscopy and by a single-crystal X-ray diffraction study.
引用
收藏
页码:C34 / C36
页数:3
相关论文
共 10 条
[1]   HIGH-VALENT PARAMAGNETIC RUTHENIUM(IV) COMPLEXES CONTAINING MULTIANIONIC CHELATING LIGANDS AS EFFICIENT CATALYSTS FOR ALKENE EPOXIDATION - X-RAY CRYSTAL-STRUCTURE OF 2[RUIV(CHBAE)(PPH3)(PYRIDINE)].ET2O.2H2O [H4CHBAE = 1,2-BIS(3,5-DICHLORO-2-HYDROXYBENZAMIDO)ETHANEPYRIDIN [J].
CHE, CM ;
CHENG, WK ;
LEUNG, WH ;
MAK, TCW .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (06) :418-419
[2]   CRYSTAL AND MOLECULAR STRUCTURE OF DICHLORO(2,7-DIMETHYL-OCTA-2,6-DIENE-1,8-DIYL)RUTHENIUM(IV) DIMER [J].
COLOMBO, A ;
ALLEGRA, G .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1971, B 27 (AUG15) :1653-&
[4]   (2,7-DIMETHYLOCTADIENEDIYL)RUTHENIUM(IV) COMPLEXES - ISOMERISM AND SOLUTION EQUILIBRIA FOR DICHLOROBIS(MU-CHLORO)BIS[(1-3-ETA-6-8-ETA)-2,7-DIMETHYLOCTADIENEDIYL]DIRUTHENIUM(IV) AND RELATED MONOMERIC SOLVATES [J].
COX, DN ;
ROULET, R .
INORGANIC CHEMISTRY, 1990, 29 (07) :1360-1365
[5]  
FURHOLZ U, 1984, J AM CHEM SOC, V106, P121
[6]   SOME 2,7-DIMETHYLOCTA-2,6-DIENE-1,8-DIYLRUTHENIUM PHOSPHINE, FLUOROPHOSPHINE AND CARBONYL-COMPLEXES [J].
HEAD, RA ;
NIXON, JF ;
SWAIN, JR ;
WOODARD, CM .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 76 (03) :393-400
[8]  
HITCHCOCK PB, 1975, J ORGANOMET CHEM, V86, pC34, DOI 10.1016/S0022-328X(00)89625-4
[9]  
PORRI L, 1965, TETRAHEDRON LETT, P4187
[10]   ARENERUTHENIUM(II) CARBOXYLATES - REACTIONS WITH LIGANDS AND THE X-RAY STRUCTURE OF THE PARA-CYMENE PYRAZINE COMPLEX [RU(ETA-P-MEC6H4CHME2)CL(PYZ)2]PF6 [J].
TOCHER, DA ;
GOULD, RO ;
STEPHENSON, TA ;
BENNETT, MA ;
ENNETT, JP ;
MATHESON, TW ;
SAWYER, L ;
SHAH, VK .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (08) :1571-1581