SYNTHESIS AND REACTIONS OF ISOTHIOCYANATE-SUBSTITUTED ALLENES AND 1,3-BUTADIENES

被引：39

作者：

BANERT, K

HUCKSTADT, H

VROBEL, K

机构：

[1] Fachbereich 8, Organische Chemie II, Universität‐Gesamthochschule Siegen, D-W-5900, Adolf‐Reichwein‐Strasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 01期

关键词：

D O I：

10.1002/anie.199200901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unusually reactive towards nucleophiles are the allyl isothiocyanates 1 (R1, R2 = H or Me), which can be prepared from the easily accessible propargyl thiocyanates by [3,3]-sigmatropic shifts. Similar isomerization reactions also allow the preparation of 2 and 3 (R = H, Me). These compounds are suitable for the synthesis of heterocycles and for cycloaddition reactions.

引用

页码：90 / 92

页数：3

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