OXIDATIVE POLYMERIZATION OF PYRROLE IN POLYMER MATRIX

被引：28

作者：

SARAC, AS ^{[1
]}

USTAMEHMETOGLU, B ^{[1
]}

MUSTAFAEV, MI ^{[1
]}

ERBIL, C ^{[1
]}

UZELLI, G ^{[1
]}

机构：

[1] BAKU STATE UNIV,DEPT CHEM,BAKU,AZERBAIJAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1995年 / 33卷 / 10期

关键词：

MATRIX POLYMERIZATION; POLYPYRROLE; CHEMICAL SYNTHESIS; INTERPOLYMER COMPLEX; WATER SOLUBLE POLYPYRROLE;

D O I：

10.1002/pola.1995.080331004

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The oxidative matrix polymerization of pyrrole (Py) by Ce(IV) in the presence of Polyacrylic acid (PAA) has been studied to obtain water-soluble and insoluble products. The role of the PAA, Pyrrole, and Ce(IV) concentration, order of component addition, the structure of polymer matrix [PAA, Hydroxy Ethyl Cellulose (HES), Poly-N-vinylpyrrolidone (PVP)], and model unit of PAA (propionic acid), on the polymerization system were investigated. Interaction of PAA with insoluble polypyrrole (PPy) and the interpolymer complex formation were investigated along with the aggregation of PPy onto the matrix polymer followed by spectral shifts. FTIR results of insoluble products obtained from the PAA-Py-Ce(IV) system and solubility of the system is explained in light of the mechanism of the polymerization of pyrrole on the polymer matrix. (C) 1995 John Wiley and Sons, Inc.

引用

页码：1581 / 1587

页数：7

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