MICHAEL ADDITION OF GRIGNARD REAGENTS TO ALKYNYL-1-PHOSPHINE SULFIDES

被引：23

作者：

AGUIAR, AM

IRELAN, JRS

机构：

[1] Department of Chemistry, Tulane University, New Orleans

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 12期

关键词：

D O I：

10.1021/jo01264a059

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Michael addition of Grignard reagents to t-alkynyl-1-phosphine sulfides occurs in the presence of cuprous chloride. A variety of examples of this new reaction are described. The structures of the resulting vinylphosphine sulfides and oxides were elucidated using proton nmr. © 1969, American Chemical Society. All rights reserved.

引用

页码：4030 / &

共 5 条

[1] AGUIAR AM, IN PRESS
[2] CHARRIER C, 1964, CR HEBD ACAD SCI, V258, P1537
[3] CHEMISTRY OF CARBANIONS .12. ROLE OF COPPER INCONJUGATE ADDITION OF ORGANOMETALLIC REAGENTS
HOUSE, HO
RESPESS, WL
WHITESID.GM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (10) : 3128 - &
[4] ALKALI-PHOSPHORVERBINDUNGEN UND IHR REAKTIVES VERHALTEN .12. ZUR REAKTION DER ALKALIPHOSPHIDE MEPR2 MIT CHLOR-PHENYLACETYLEN
ISSLEIB, K
HARZFELD, G
[J]. CHEMISCHE BERICHTE-RECUEIL, 1962, 95 (01): : 268 - &
[5] Kharasch M.S., 1954, GRIGNARD REACTIONS N, P219

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