ON THE CONFIGURATIONAL STABILITY OF ALPHA-BROMO-ALKYLLITHIUM COMPOUNDS

被引：27

作者：

HOFFMANN, RW

RUHLAND, T

BEWERSDORF, M

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 03期

关键词：

D O I：

10.1039/c39910000195

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1-Bromopentyllithium 1, a typical 'bromocarbenoid,' has been established to be chiral and configurationally stable at - 120-degrees-C by a test based on kinetic resolution; likewise, diastereoisomeric 1-bromoalkyllithium compounds were generated from the bromo-tin compounds 5 and 6 and found to be configurationally stable at - 110-degrees-C.

引用

页码：195 / 196

页数：2

共 10 条

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