ON THE CONFIGURATIONAL STABILITY OF ALPHA-BROMO-ALKYLLITHIUM COMPOUNDS

被引:27
作者
HOFFMANN, RW
RUHLAND, T
BEWERSDORF, M
机构
关键词
D O I
10.1039/c39910000195
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1-Bromopentyllithium 1, a typical 'bromocarbenoid,' has been established to be chiral and configurationally stable at - 120-degrees-C by a test based on kinetic resolution; likewise, diastereoisomeric 1-bromoalkyllithium compounds were generated from the bromo-tin compounds 5 and 6 and found to be configurationally stable at - 110-degrees-C.
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页码:195 / 196
页数:2
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