MIXED PHOSPHORUS(III) PHOSPHORUS(V) OXIDE CHALCONIDES

被引：31

作者：

WALKER, ML ^{[1
]}

PECKENPAUGH, DE ^{[1
]}

MILLS, JL ^{[1
]}

机构：

[1] TEXAS TECH UNIV,DEPT CHEM,LUBBOCK,TX 79409

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 10期

关键词：

D O I：

10.1021/ic50200a032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetraphosphorus hexaoxide, P4O6, and tetraphosphorus heptaoxide, P4O7, were oxidized by reaction with P4S10 or P4Se10 to extend a class of adamantanoid structures based upon the P4O6 cage. The redistribution reactions of P4O10 with [FORMULA OMMITED] were identified, and all were found to be structural derivatives of the P4O6 cage. Phosphorus-31 chemical shifts are compared and related to available structural information. The reaction of P4O7S to produce P4O6S2 and P4O8 is also discussed. An improved preparation of P4O7 is presented. © 1979, American Chemical Society. All rights reserved.

引用

页码：2792 / 2796

页数：5

共 25 条

[1]

ABEL EW, 1964, J CHEM SOC, P5585

[2]

Armitage DA, 1972, INORGANIC RINGS CAGE

[3] SMOOTH OXIDATION OF PHOSPHORUS CLOSO-TYPE COMPOUNDS - PREPARATION AND CHARACTERIZATION OF CLOSO-HEXA-N-METHYLOXYTHIOPHOSPHORIMIDES P4(NME)6SNO4-N (N=0-3) AND AN IMPROVED SYNTHESIS FOR CLOSO-HEXA-N-METHYLTHIOPHOSPHORIMIDES [J].