NOVEL BEHAVIOR OF DIALKYLAMINO-SUBSTITUTED PROPARGYLIC ALCOHOLS IN REACTIONS WITH ARENE RUTHENIUM(II) COMPLEXES

被引：25

作者：

PILETTE, D ^{[1
]}

MOREAU, S ^{[1
]}

LEBOZEC, H ^{[1
]}

DIXNEUF, PH ^{[1
]}

CORRIGAN, JF ^{[1
]}

CARTY, AJ ^{[1
]}

机构：

[1] UNIV WATERLOO,DEPT CHEM,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO N2L 3G1,ON,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 04期

关键词：

D O I：

10.1039/c39940000409

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of arene ruthenium(II)derivatives(C(6)Me(4)R(2))RuCl2(L)(R=H,Me;L=PMe(3),PPh(3)) with the prop-2-ynylic alcohol derivative HC=C-C(H)(OH)(C6H4-p-NMe(2)) in dichloromethane results in the formation of new oxametallacyclic ruthenium(II) complexes {(C(6)Me(4)R(2))Ru[CH=C(C6H4-p-NMe(2))CHO](L)}PF6 via an unprecedented 1,2-migration of the dimethylaminophenyl substituent; the structure of one compound (R=H;L=PPh(3)) is determined by an X-ray crystal structure analysis.

引用

页码：409 / 410

页数：2

共 13 条

[1] STUDIES IN STEREOCHEMISTRY .5. PHENONIUM SULFONATE ION-PAIRS AS INTERMEDIATES IN THE INTRAMOLECULAR REARRANGEMENTS AND SOLVOLYSIS REACTIONS THAT OCCUR IN THE 3-PHENYL-2-BUTANOL SYSTEM
CRAM, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (09) : 2129 - 2137
[2] CARBON-HYDROGEN BOND ACTIVATION BY TRANSITION-METAL COMPLEXES - OXIDATIVE ADDITION OF ALKYL METHACRYLATE TO RUTHENIUM - STRUCTURE OF HYDRIDO(2-N-BUTOXYCARBONYLPROPENYL-C1,O)TRIS-(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
KOMIYA, S
ITO, T
COWIE, M
YAMAMOTO, A
IBERS, JA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (13) : 3874 - 3884
[3] MARCH J, 1985, ADV ORG CHEM, P942
[4] STABLE CARBOCATIONS .195. REARRANGEMENT OF ETHYLENEBENZENIUM IONS TO ALPHA-PHENYLETHYL (STYRYL) CATIONS - DETERMINATION OF RELATIVE ENERGIES OF SIGMA-BRIDGED ETHYLENEBENZENIUM ION, OPEN-CHAIN 2-PHENYLETHYL CATION, AND ALPHA-STYRYL CATION
OLAH, GA
SPEAR, RJ
FORSYTH, DA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (20) : 6284 - 6289
[5] STABLE CARBONIUM IONS .31. P-ANISONIUM AND METHYLPHENONIUM ION FORMATION VIA ARYL PARTICIPATION IN STRONG ACID SOLUTION
OLAH, GA
COMISARO.MB
NAMANWOR.E
RAMSEY, B
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (20) : 5259 - &
[6] STABLE CARBOCATIONS .125. PROTON AND C-13 MAGNETIC-RESONANCE STUDIES OF PHENYLCARBONIUM IONS (BENZYL CATIONS) - EFFECT OF SUBSTITUENTS ON STABILITY OF CARBOCATIONS
OLAH, GA
PORTER, RD
WHITE, AM
JEUELL, CL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (06) : 2044 - &
[7] OLAH GA, 1968, CARBONIUM IONS, P237
[8] ONE-STEP SYNTHESIS OF ALKENYLOXY ALKENYLCARBENE COMPLEXES AND THE UNPRECEDENTED FORMATION OF AN ETA-5-ALLYL-ALKENE RUTHENIUM COMPLEX
PILETTE, D
LEBOZEC, H
ROMERO, A
DIXNEUF, PH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) : 1220 - 1222
[9] ACTIVATION OF 2-PROPYN-1-OL DERIVATIVES BY (ARENE)RUTHENIUM(II) COMPLEXES - NEW ROUTE TO (ALKENYLCARBENE)METAL AND (POLYENYLCARBENE)METAL COMPLEXES
PILETTE, D
OUZZINE, K
LEBOZEC, H
DIXNEUF, PH
RICKARD, CEF
ROPER, WR
[J]. ORGANOMETALLICS, 1992, 11 (02) : 809 - 817
[10] ROMERO A, 1990, ANGEW CHEM INT EDIT, V29, P215

← 1 2 →