COMPLETE DESULFURIZATION OF DIETHYLDITHIOCARBAMATO LIGANDS TO GIVE A PENTARUTHENIUM CLUSTER CONTAINING DIETHYLAMINOMETHYLIDYNE LIGANDS

被引：23

作者：

DEEMING, AJ

VAISH, R

机构：

[1] Department of Chemistry, University College London, London, WC1H 0AJ

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80372-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative addition of the disulfide Et2NC(S)SSC(S)NEt2 to the cluster [Ru3(CO)12] leads to the diethyldithiocarbamato complex, [Ru(Et2NCS2)2(CO)2]3, which reacts with more [Ru3(CO)12] to give mainly the pentanuclear cluster, [Ru5(mu4-S)2(mu-CNEt2)2(CO)11] 4, containing bridging diethylaminomethylidyne ligands derived by cleavage of both C-S bonds of both dithiocarbamato ligands.

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页码：C8 / C10

页数：3

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