HETERONUCLEAR COORDINATION-COMPOUNDS WITH METAL-METAL BONDS .8. NEW HETERODINUCLEAR COMPLEXES WITH BONDS BETWEEN COPPER(I) AND MANGANESE(-I), IRON(-I), OR COBALT(-I)

被引：5

作者：

APFEL, J ^{[1
]}

KLUFERS, P ^{[1
]}

SELLE, A ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,ENGESSERSTR,GEBAUDE 3045,D-76128 KARLSRUHE,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 02期

关键词：

HETERONUCLEAR METAL COMPLEXES; METAL METAL BONDS; COPPER; CARBONYLMANGANATE; NITROSYL-CARBONYL-FERRATE; CARBONYLCOBALTATE;

D O I：

10.1002/zaac.19956210219

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(en)Cu-Mn(CO)5] (1a), [(dien)Cu-Mn(CO)5] (1b), [(en)Cu-Fe(CO)3(NO)] (2a), [(dien)Cu-Fe(CO)3(NO)] (2b), [(en)Cu-Co(CO)4] (3a), and [(dien)Cu-Co(CO)4] (3b) are new heterobinuclear metal-metal bonded complexes. The geometry of the [Mn(CO)5]-, [Fe(CO)3(NO)]-, and [Co(CO)4]- ions is distorted only to a less extend in accord with a heteropolar bond to copper.

引用

页码：323 / 330

页数：8

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