PHOTOLYSIS OF FERROCENYL-OLEFINS AND FERROCENYL-ETHERS IN ALCOHOLS

被引:9
作者
BAKER, C [1 ]
HORSPOOL, WM [1 ]
机构
[1] UNIV DUNDEE,DEPT CHEM,DUNDEE DD1 4HN,SCOTLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 07期
关键词
D O I
10.1039/p19790001862
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The irradiation of solutions of 2-ferrocenylpropene and ferrocenylethylene in methanol and ethanol has been studied. The primary photochemical process is interpreted as involving ferrocenyl carbocation intermediates which yield ferrocenyl ethers. These ethers are themselves photolabile, yielding 2-ferrocenylpropane and 2,3-diferrocenyl-2,3-dimethylbutane from 2-ferrocenylpropene, and ferrocenylethane and 2,3-diferrocenylbutane from ferrocenylethylene. These latter reactions are thought to involve ferrocenyl free radicals.
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页码:1862 / 1865
页数:4
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