PHOTOLYSIS OF FERROCENYL-OLEFINS AND FERROCENYL-ETHERS IN ALCOHOLS

被引：9

作者：

BAKER, C ^{[1
]}

HORSPOOL, WM ^{[1
]}

机构：

[1] UNIV DUNDEE,DEPT CHEM,DUNDEE DD1 4HN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 07期

关键词：

D O I：

10.1039/p19790001862

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The irradiation of solutions of 2-ferrocenylpropene and ferrocenylethylene in methanol and ethanol has been studied. The primary photochemical process is interpreted as involving ferrocenyl carbocation intermediates which yield ferrocenyl ethers. These ethers are themselves photolabile, yielding 2-ferrocenylpropane and 2,3-diferrocenyl-2,3-dimethylbutane from 2-ferrocenylpropene, and ferrocenylethane and 2,3-diferrocenylbutane from ferrocenylethylene. These latter reactions are thought to involve ferrocenyl free radicals.

引用

页码：1862 / 1865

页数：4

共 33 条

[1] FERROCENE-1,1'-DISULFONYL AZIDE AND 2,4,6-TRIMETHYLPYRIDINIUM FERROCENESULFONYL YLIDE - SYNTHESIS AND DECOMPOSITION
ABRAMOVITCH, RA
HOLCOMB, WD
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (03) : 491 - 497
[2] AKIYAMA T, 1973, B CHEM SOC JPN, V46, P1851, DOI 10.1246/bcsj.46.1851
[3] MECHANISM OF PHOTO-SUBSTITUTION OF FERROCENE IN HALOALKANE-ETHANOL SOLUTIONS
AKIYAMA, T
SUGIMORI, A
HERMANN, H
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1973, 46 (06) : 1855 - 1859
[4] DERIVATIVES OF DICYCLOPENTADIENYLIRON
ARIMOTO, FS
HAVEN, AC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (23) : 6295 - 6297
[5] BAKER C, 1971, CHEM COMM, P615
[6] Bozak R. E., 2007, ADV PHOTOCHEM, P227, DOI DOI 10.1002/9780470133385.CH5
[7] Cais M, 1966, ORGANOMET CHEM REV, V1, P435
[8] PHOTOCHEMICAL REACTIONS OF FERROCENYL KETONES
COYLE, JD
MARR, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 60 (01) : 153 - 156
[9] APPLICATION OF HIGH-PRESSURE LIQUID-LIQUID-CHROMATOGRAPHY (LLC) IN CHEMISTRY OF METALLOCENES
EBERHARDT, R
LEHNER, H
SCHLOGL, K
[J]. MONATSHEFTE FUR CHEMIE, 1973, 104 (05): : 1409 - 1420
[10] ELLIS AF, 1963, DISSERT ABSTR, V24, P510

← 1 2 3 4 →