A ROUTE TO UNSATURATED SPIROKETALS FROM PHENYLTHIO HEX-2-ENOPYRANOSIDES VIA SEQUENTIAL ALKYLATION, ALLYLIC REARRANGEMENT AND INTRAMOLECULAR GLYCOSIDATION

被引：18

作者：

GOMEZ, AM

VALVERDE, S

FRASERREID, B

机构：

[1] INST QUIM ORGAN GEN,E-28006 MADRID,SPAIN

[2] DUKE UNIV,DEPT CHEM,PAUL M GROSS CHEM LAB,DURHAM,NC 27706

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 17期

关键词：

D O I：

10.1039/c39910001207

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkylated phenylthio hex-2-enopyranosides readily undergo 1,3-phenylthio migration, and treatment of the resulting enol ether with N-iodosuccinimide gives an allyl-oxocarbenium ion which can be trapped intramolecularly by a suitably located hydroxy group to yield an unsaturated spiroketal.

引用

页码：1207 / 1208

页数：2

共 19 条

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