SYNTHESIS AND PROPERTIES OF A NOVEL NICKEL(II) CYCLAM (CYCLAM=1,4,8,11-TETRAAZACYCLOTETRADECANE) COMPLEX COVALENTLY ATTACHED TO RU(BPY)(3)(2+) (BPY=2,2'-BIPYRIDYL)

被引：10

作者：

BU, XH

CHEN, YT

SHIONOYA, M

KIMURA, E

机构：

[1] NANKAI UNIV,DEPT CHEM,TIANJIN 300071,PEOPLES R CHINA

[2] HIROSHIMA UNIV,SCH MED,DEPT MED CHEM,HIROSHIMA 734,JAPAN

来源：

POLYHEDRON | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1016/S0277-5387(00)86610-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A ditopic ligand bpy-cyclam (1) and its heterometallo-binuclear complex Ru (bpy)(2)(bpy-cyclam-Ni)(4+) (3) as well as the related intermediate complex Ru(bpy)(2)(bpy-cyclam-2H)(4+) (2) have been synthesized and characterized. Their spectroscopic and redox properties have been studied. An efficient intramolecular fluorescence quenching phenomenon was observed for complex 3, which was composed of an Ru(bpy)(3)(2+) core and an Ni(cyclam)(2+) subunit, and is shown to be an interesting hybrid molecule with novel functions.

引用

页码：325 / 331

页数：7

共 27 条

[1]

BALZANI V, 1991, SUPRAMOLECULAR PHOTO, P72

[2] NICKEL(II) CYCLAM - AN EXTREMELY SELECTIVE ELECTROCATALYST FOR REDUCTION OF CO2 IN WATER [J].