MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .179. ELECTRON IMPACT INDUCED REARRANGEMENTS OF 1-PHENYLHEPTENES . FURTHER EVIDENCE FOR DOUBLE BOND LABILITY

被引：29

作者：

GERRARD, AF

DJERASSI, C

机构：

[1] Department of Chemistry, Stanford University, Stanford

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 24期

关键词：

D O I：

10.1021/ja01052a045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mass spectra of a series of isomeric 1-phenylheptenes have been measured. Evidence for extensive hydrogen and even phenyl rearrangement ions has been uncovered through the use of deuterium and 18C-labeled analogs. Mass spectrometry is not a very useful tool for differentiating between such double bond isomers due to the ease of double bond migration after ionization. © 1969, American Chemical Society. All rights reserved.

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页码：6808 / &

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