ANIONIC SYNTHESIS OF CHAIN-END FUNCTIONALIZED POLYMERS

被引：28

作者：

QUIRK, RP

YIN, J

GUO, SH

HU, XW

SUMMERS, G

KIM, JG

ZHU, LF

SCHOCK, LE

机构：

[1] Institute of Polymer Science, University of Akron, Akron, Ohio

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1990年 / 32卷

关键词：

D O I：

10.1002/masy.19900320106

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The use of living, alkyllithium‐initated anionic polymerization to prepare chain‐end functionalization reactions is discussed. The scope and limitations of termination reactions with a variety of electrophilic species is illustrated for carbonation, hydroxyethylation, amination, and sulfonation. The methodology of using substituted 1,1‐diphenylethylenes to provide a general, quantitative functionalization method is outlined and illustrated with examples of phenol end‐functionalization and amination. Copyright © 1990 Hüthig & Wepf Verlag

引用

页码：47 / 59

页数：13

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