DETERMINATION OF THE EQUATION-OF-STATE PARAMETERS OF POLY(METHYL ACRYLATE)

被引：15

作者：

BRUNACCI, A ^{[1
]}

PEDEMONTE, E ^{[1
]}

TURTURRO, A ^{[1
]}

机构：

[1] CNR,CTR STUDI CHIM FIS MACROMOLEC SINTET & NAT,I-16132 GENOA,ITALY

来源：

POLYMER | 1992年 / 33卷 / 20期

关键词：

POLY(METHYL ACRYLATE); SPECIFIC VOLUME; THERMAL EXPANSION COEFFICIENT; THERMAL PRESSURE COEFFICIENT; REDUCED EQUATION OF STATE;

D O I：

10.1016/0032-3861(92)90292-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The specific volume and thermal pressure coefficient for poly(methyl acrylate) of M(w) = 30 600 have been accurately determined. Results are compared with the Prigogine Flory reduced equation of state employed in the theory of solutions. The characteristic parameters v*, T* and p* required for the treatment of poly(methyl acrylate) solutions and blends are obtained from the experimental results.

引用

页码：4428 / 4431

页数：4

共 12 条

[1] THERMODYNAMIC PROPERTIES OF MIXTURES OF SMALL NONPOLAR MOLECULES
ABE, A
FLORY, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) : 1838 - &
[2] INTERMOLECULAR FORCES AND CHAIN FLEXIBILITIES IN POLYMERS .2. INTERNAL PRESSURES OF POLYMERS
ALLEN, G
GEE, G
MANGARAJ, D
SIMS, D
WILSON, GJ
[J]. POLYMER, 1960, 1 (04) : 467 - 476
[3] [Anonymous], 1957, MOL THEORY SOLUTIONS
[4] THERMODYNAMICS OF POLYMER SOLUTIONS .1. NATURAL RUBBER AND BENZENE
EICHINGER, BE
FLORY, PJ
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (548P): : 2035 - +
[5] EICHINGHER BE, 1968, MACROMOLECULES, V3, P285
[6] STATISTICAL THERMODYNAMICS OF CHAIN MOLECULE LIQUIDS .I. EQUATION OF STATE FOR NORMAL PARAFFIN HYDROCARBONS
FLORY, PJ
ORWOLL, RA
VRIJ, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (17) : 3507 - +
[7] STATISTICAL THERMODYNAMICS OF CHAIN MOLECULE LIQUIDS .2. LIQUID MIXTURES OF NORMAL PARAFFIN HYDROCARBONS
FLORY, PJ
ORWOLL, RA
VRIJ, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (17) : 3515 - &
[8] STATISTICAL THERMODYNAMICS OF LIQUID MIXTURES
FLORY, PJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (09) : 1833 - +
[9] EQUATION-OF-STATE PARAMETERS FOR POLYSTYRENE
HOCKER, H
BLAKE, GJ
FLORY, PJ
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1971, 67 (584): : 2251 - +
[10] TURTURRO A, 1969, MAKROMOLEKUL CHEM, V124, P160

← 1 2 →