FORMATION OF POLY(2,5-DIBUTOXY-1,4-PHENYLENEVINYLENE) AT ROOM-TEMPERATURE IN CHCL3 CATALYZED BY CHCL3 PHOTOPRODUCTS

被引：17

作者：

DELMOTTE, A

BIESEMANS, M

RAHIER, H

GIELEN, M

MEIJER, EW

机构：

[1] FREE UNIV BRUSSELS,FYSC,B-1050 BRUSSELS,BELGIUM

[2] EINDHOVEN UNIV TECHNOL,DEPT ORGAN CHEM,5600 MB EINDHOVEN,NETHERLANDS

来源：

SYNTHETIC METALS | 1993年 / 58卷 / 03期

关键词：

D O I：

10.1016/0379-6779(93)91141-N

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A convenient, mild preparation of poly(2,5-dibutoxy-1,4-phenylenevinylene) (DBOPPV) using a modified precursor route is reported. The conversion of the. methoxy pendent precursor polymer into its conjugated form is performed in chloroform by the elimination of methanol at room temperature, yielding DBOPPV as a red solution. The elimination is thought to be catalysed by the acid photoproducts of chloroform.

引用

收藏

页码：325 / 334

页数：10

相关论文

共 11 条

[1] SOLUBLE SUBSTITUTED PPV CONDUCTING POLYMERS - SPECTROSCOPIC STUDIES [J].

ASKARI, SH ;

RUGHOOPUTH, SD ;

WUDL, F .

SYNTHETIC METALS, 1989, 29 (01) :E129-E134

[2] CHARACTERIZATION OF POLY(PHENYLENEVINYLENE) BY INFRARED AND OPTICAL-ABSORPTION [J].

BRADLEY, DDC ;

EVANS, GP ;

FRIEND, RH .

SYNTHETIC METALS, 1987, 17 (1-3) :651-656

[3] CHEMICAL TUNING OF ELECTROLUMINESCENT COPOLYMERS TO IMPROVE EMISSION EFFICIENCIES AND ALLOW PATTERNING [J].

BURN, PL ;

HOLMES, AB ;

KRAFT, A ;

BRADLEY, DDC ;

BROWN, AR ;

FRIEND, RH ;

GYMER, RW .

NATURE, 1992, 356 (6364) :47-49

[4] LIGHT-EMITTING-DIODES BASED ON CONJUGATED POLYMERS [J].

BURROUGHES, JH ;

BRADLEY, DDC ;

BROWN, AR ;

MARKS, RN ;

MACKAY, K ;

FRIEND, RH ;

BURN, PL ;

HOLMES, AB .

NATURE, 1990, 347 (6293) :539-541

[5] HIGHLY CONDUCTING, IODINE-DOPED ARYLENE VINYLENE COPOLYMERS WITH DIALKOXYPHENYLENE UNITS [J].

LENZ, RW ;

HAN, CC ;

LUX, M .

POLYMER, 1989, 30 (06) :1041-1047

[6] SYNTHESIS OF POLY(2,5-DIMETHOXY-PARA-PHENYLENEVINYLENE) FILM THROUGH A NEW PRECURSOR POLYMER [J].

MOMII, T ;

TOKITO, S ;

TSUTSUI, T ;

SAITO, S .

CHEMISTRY LETTERS, 1988, (07) :1201-1204

[7]

MURASE I, 1984, POLYM COMMUN, V25, P327

[8] SYNTHESIS OF NEW CONDUCTIVE POLYMERS [J].

NAARMANN, H .

SYNTHETIC METALS, 1987, 17 (1-3) :223-228

[9] SOLID-STATE CROSS POLARIZATION MAGIC ANGLE SPINNING C-13 NMR INVESTIGATION OF ALKOXY-SUBSTITUTED POLY(PARA-PHENYLENE VINYLENE) HOMOPOLYMERS AND COPOLYMERS [J].

NOUWEN, J ;

VANDERZANDE, D ;

MARTENS, H ;

GELAN, J ;

YANG, Z ;

GEISE, H .

SYNTHETIC METALS, 1992, 46 (01) :23-44

[10]

PATIL AO, 1989, SYNTHETIC MET, V29, pE115