ELECTRIC FIELD-ASSOCIATED DEFORMATION OF POLYELECTROLYTE GEL NEAR A PHASE-TRANSITION POINT

The influence of dc electric fields on sodium acrylate-acrylamide copolymer gel near a phase transition point in acetone-water mixtures containing NaOH was studied. In the mixtures free of NaOH, the shrunken-state gel near a phase transition point was not influenced by dc electric fields, while the swollen-state gel near it shrank from its part facing to the positive electrode in dc electric fields. In the presence of NaOH, unprecedented swelling of the shrunken-state gel has been observed. The swollen-state gel showed swelling or shrinking in the field. The type of deformation was determined by the concentration of NaOH. The drift of mobile ions played a role in the deformation. The shrinking occurred through the conformational change of polymer network caused by the drift. The swelling was observed by the change of the osmotic pressure based upon the ion concentration difference between the inside and the outside of a gel.