HYDROBORATION/INTRAMOLECULAR REDUCTION OF ALLYL KETONES WITH (DIISOPINOCAMPHEYL)BORANE - A CONVENIENT SYNTHESIS OF ENANTIOMERICALLY ENRICHED 1,4-DIOLS

被引：19

作者：

MOLANDER, GA

BOBBITT, KL

机构：

[1] Department of Chemistry Biochemistry, University of Colorado at Boulder, Colorado 80309-0215, Boulder

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 10期

关键词：

D O I：

10.1021/jo00089a005

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The hydroboration of a variety of allyl ketones with (-)-(diisopinocampheyl)borane precedes a highly stereoselective intramolecular reduction of the ketone, providing a convenient procedure for the preparation of enantiomerically enriched alcohols.

引用

页码：2676 / 2678

页数：3

共 25 条

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