DERIVATIVE CHEMISTRY OF CATIONIC TRIRUTHENIUM CARBONYL CLUSTER COMPOUNDS - REACTIONS LEADING TO A NEUTRAL HEXANUCLEAR COMPLEX CONSISTING OF 2 VERTEX-LINKED METAL TRIANGLES

被引：20

作者：

CABEZA, JA ^{[1
]}

DELRIO, I ^{[1
]}

RIERA, V ^{[1
]}

GREPIONI, F ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 07期

关键词：

D O I：

10.1021/om00007a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ru-6(mu(3)-ampy)(2)(CO)(18)] (1; Hampy = 2-amino-6-methylpyridine), the first neutral hexanuclear carbonyl cluster complex consisting of two closed trimetal units connected by only one metal-metal bond (X-ray structure), has been prepared by (a) reaction of the cationic precursor [Ru-3(mu(3)-ampy)(CO)(10)](+) (2) with aqueous NaOH, (b) reaction of complex 2 with the anion [Ru-3(mu(3)-ampy)(CO)(9)](-), and (c) zinc reduction of complex 2.

引用

页码：3124 / 3126

页数：3

共 21 条

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