ADDITION OF METHYLENE GROUPS TO FE3(CO)9(MU-3-TE)2

被引：34

作者：

MATHUR, P ^{[1
]}

REDDY, VD ^{[1
]}

BOHRA, R ^{[1
]}

机构：

[1] UNIV RAJASTHAN,DEPT CHEM,JAIPUR 302004,RAJASTHAN,INDIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 401卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)86230-N

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

At room temperature, Fe3(CO)9(mu-Te)2 reacts with diazomethane to form (CO)6Fe2(mu-TeCH2Te) (I) and (CO)6Fe2Te2(CH2)2 (II). Complexes I and II have been separated by chromatography and characterised by IR and NMR spectroscopy, mass spectrometry and microanalysis. Complex I was also subjected to an X-ray diffraction study. The crystals are monoclinic, space group P2(1)/c with a = 6.864(2), b = 13.926(3), c = 14.159(3) angstrom, beta = 104.43(2)-degrees, V = 1310.6(5) angstrom, Z = 4, D(c) = 2.79 g cm-3 and R = 0.043.

引用

页码：339 / 346

页数：8

共 42 条

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