ALKALINE-EARTH METAL-COMPLEXES CONTAINING DEPROTONATED ORGANIC-ACIDS AND WATER - PREPARATION, STRUCTURES AND A NEW SYNTHETIC STRATEGY

被引：25

作者：

MIKULCIK, P

RAITHBY, PR

SNAITH, R

WRIGHT, DS

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8046 GARCHING,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 04期

关键词：

D O I：

10.1002/anie.199104281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of an organic acid with solid metal hydroxides in hydrocarbon solvent in the presence of a Lewis base such as hexamethylphosphoric triamide (HMPA) affords the metal complexes of the title according to Equation (a). The complex Ox2Ca.2HMPA.2H2O can be prepared from Ca(OH)2, 2-mercaptobenzoxazol (OxH) and HMPA in this direct synthesis. A striking feature of its structure is the intra- and intermolecular S ... H-O hydrogen bonds.

引用

页码：428 / 430

页数：3

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