KINETICS AND MECHANISM OF THE SUBSTITUTION OF [(NH3)5RUIII(EDTA)RUIII(H2O)]2+ (EDTA = ETHYLENE-DIAMINETETRAACETATE) BY THIOUREA IN AQUEOUS-SOLUTION

被引：13

作者：

CHATTERJEE, D

BAJAJ, HC

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 07期

关键词：

D O I：

10.1039/dt9930001065

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The substitution of the H2O ligand of the complex [(NH3)5Ru(III)(edta)Ru(III)(H2O)]2+ (edta = ethylenediaminetetraacetate) by thiourea was studied spectrophotometrically. Rate and activation parameters are found to be consistent with an associative interchange mechanism. Experimental results are discussed with reference to literature data for the corresponding substitution of mononuclear [Ru(III)(edta)(H2O)]-.

引用

页码：1065 / 1067

页数：3

共 14 条

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