ARSENIC SPECIATION BY COUPLING HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY WITH INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY

被引:86
作者
DEMESMAY, C [1 ]
OLLE, M [1 ]
PORTHAULT, M [1 ]
机构
[1] UNIV CLAUDE BERNARD,SCI ANALYT LAB,UA 0435,F-69622 VILLEURBANNE,FRANCE
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1994年 / 348卷 / 03期
关键词
D O I
10.1007/BF00325361
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
An ICP-MS detector in combination with HPLC has been evaluated for the analysis of six arsenic compounds. The influence of the presence of an organic modifier in the mobile phase on arsenic response and the quality parameters of the analysis are discussed. Detection limits for arsenic species under study range from 10 to 30 pg. The determination of arsenic compounds in solutions simulating fish or sediment extracts has been used to demonstrate the applicability of this technique.
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页码:205 / 210
页数:6
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