SYNTHESIS OF PYROPHEOPHYTIN-ANTHRAQUINONE LINKED MOLECULES AS MODELS FOR THE STUDY OF PHOTOINDUCED ELECTRON-TRANSFER

被引：18

作者：

TAUBER, AY

KOSTIAINEN, RK

HYNNINEN, PH

机构：

[1] UNIV HELSINKI,DEPT CHEM,SF-00014 HELSINKI,FINLAND

[2] ENVIRONM LAB HELSINKI,SF-00530 HELSINKI,FINLAND

来源：

TETRAHEDRON | 1994年 / 50卷 / 16期

关键词：

D O I：

10.1016/S0040-4020(01)85011-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of pyropheophytin-anthraquinone, compounds with the quinone with the quinoine covalently linked to the P4 allylic position of the phytyl chain is described. The results of preliminary conformational studies are reported for the two P4 stereoisomers obtained. These results suggest differences in die orientation of the anthraquinonyl-phytyl moiety relative to the phorbin macrocycle in the isomers.

引用

页码：4723 / 4732

页数：10

共 22 条

[1]

Abraham R. J., 1991, CHLOROPHYLLS, P797

[2] SYNTHESIS AND PROPERTIES OF PHEOPHORBIDE-QUINONE COMPOUNDS [J].